三峡库区消落区表层沉积物磷吸附特征   总被引：2，自引：0，他引：2       下载免费PDF全文

曹琳  吉芳英  林茂  黎司  王图锦 《水科学进展》2011,22(1):89-96

以三峡库区消落区表层沉积物为研究对象,通过对干湿交替沉积物中磷的赋存形式、吸附等温曲线的分析,揭示了干湿交替过程中沉积物磷的分布规律、吸附特征以及磷的源汇变化。结果表明:上覆水总磷变化呈现11月总磷<5月总磷<8月总磷。消落区覆水到出露沉积物最大磷吸附量、土壤最大缓冲能力在增加,磷零吸持平衡浓度、易解吸磷在降低,表明沉积物在夏季出露落干的过程中,固磷能力增强,释磷能力减弱;消落区土壤首次覆水过程中土壤磷呈现出由源到汇的转变。成库初期,覆水时沉积物主要表现为磷的积累,次年水库开闸放水排沙时,消落区表层富磷沉积物被冲刷排出。  相似文献   

Numerical studies of methane production from Class 1 gas hydrate accumulations enhanced with carbon dioxide injection   总被引：2，自引：0，他引：2  

M.D. White  S.K. WurstnerB.P. McGrail 《Marine and Petroleum Geology》2011,28(2):546-560

Class 1 gas hydrate accumulations are characterized by a permeable hydrate-bearing interval overlying a permeable interval with mobile gas, sandwiched between two impermeable intervals. Depressurization-induced dissociation is currently the favored technology for producing gas from Class 1 gas hydrate accumulations. The depressurization production technology requires heat transfer from the surrounding environment to sustain dissociation as the temperature drops toward the hydrate equilibrium point and leaves the reservoir void of gas hydrate. Production of gas hydrate accumulations by exchanging carbon dioxide with methane in the clathrate structure has been demonstrated in laboratory experiments and proposed as a field-scale technology. The carbon dioxide exchange technology has the potential for yielding higher production rates and mechanically stabilizing the reservoir by maintaining hydrate saturations. We used numerical simulation to investigate the advantages and disadvantages of using carbon dioxide injection to enhance the production of methane from Class 1 gas hydrate accumulations. Numerical simulations in this study were primarily concerned with the mechanisms and approaches of carbon dioxide injection to investigate whether methane production could be enhanced through this approach. To avoid excessive simulation execution times, a five-spot well pattern with a 500-m well spacing was approximated using a two-dimensional domain having well boundaries on the vertical sides and impermeable boundaries on the horizontal sides. Impermeable over- and under burden were included to account for heat transfer into the production interval. Simulation results indicate that low injection pressures can be used to reduce secondary hydrate formation and that direct contact of injected carbon dioxide with the methane hydrate present in the formation is limited due to bypass through the higher permeability gas zone.  相似文献   

Simultaneous solution for water,heat and salt balances in a Mediterranean coastal lagoon (Mar Menor,Spain)     

V. Martínez-Alvarez  B. Gallego-ElviraJ.F. Maestre-Valero  M. Tanguy 《Estuarine, Coastal and Shelf Science》2011

A modelling approach is proposed to evaluate the environmental dynamics of coastal lagoons. The water, heat and salt balances are addressed simultaneously, providing a better estimation of evaporation and water exchanges. Compared to traditional approaches, the model presented accounts for the effects of water salinity, heat storage and net energy advected in the water body. The model was applied daily to the Mar Menor coastal lagoon (SE Spain) from 2003 through 2006. Water exchanges with the Mediterranean Sea were estimated based on the monthly trend of the lagoon salinity and were correlated with monthly averages of wind speed. The mean daily water exchange with the sea was 1.77 hm³ d⁻¹. This exchange accounted for only 1% of the heat losses in the lagoon heat balance, and it is the most important flow in the water balance. The mean annual evaporation flux amounted to 101.3 W m⁻² (3.55 mm d⁻¹), while the sensible heat flux amounted to 19.7 W m⁻², leading to an annual Bowen ratio on the order of 0.19. To validate the model, daily water temperatures were predicted based on the daily heat balance of the water body and were compared with remote sensing data from water surface standard products.  相似文献   

Spatial variability and temporal dynamics of surface water pCO₂, ��O₂/Ar and dimethylsulfide in the Ross Sea, Antarctica     

P.D. Tortell  C. Guéguen  M.C. Long  C.D. PayneP. Lee  G.R. DiTullio 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(3):241-259

We report results from two surveys of pCO₂, biological O₂ saturation (??O₂/Ar) and dimethylsulfide (DMS) in surface waters of the Ross Sea polynya. Measurements were made during early spring (November 2006-December 2006) and mid-summer (December 2005-January 2006) using ship-board membrane inlet mass spectrometry (MIMS) for high spatial resolution (i.e. sub-km) analysis. During the early spring survey, the polynya was in the initial stages of development and exhibited a rapid increase in open water area and phytoplankton biomass over the course of our ∼3 week occupation. We observed a rapid transition from a net heterotrophic ice-covered system (supersaturated pCO₂ and undersaturated O₂) to a high productivity regime associated with a Phaeocystis-dominated phytoplankton bloom. The timing of the early spring phytoplankton bloom was closely tied to increasing sea surface temperature across the polynya, as well as reduced wind speeds and ice cover, leading to enhanced vertical stratification. There was a strong correlation between pCO₂, ??O₂/Ar, DMS and chlorophyll a (Chl a) during the spring phytoplankton bloom, indicating a strong biological imprint on gas distributions. Box model calculations suggest that pCO₂ drawdown was largely attributable to net community production, while gas exchange and shoaling mixed layers also exerted a strong control on the re-equilibration of mixed layer ??₂ with the overlying atmosphere. DMS concentrations were closely coupled to Phaeocystis biomass across the early spring polynya, with maximum concentrations exceeding 100 nM.During the summer cruise, we sampled a large net autotrophic polynya, shortly after the seasonal peak in phytoplankton productivity. Both diatoms and Phaeocystis were abundant in the phytoplankton assemblages during this time. Minimum pCO₂ was less than 100 ppm, while ??O₂/Ar exceeded 30% in some regions. Mean DMS concentrations were ∼2-fold lower than during the spring, although the range of concentrations was similar between the two surveys. There was a significant correlation between pCO₂, ??O₂/Ar and Chl a across the summer polynya, but the strength of these correlations and the slope of O₂ vs. CO₂ relationship were significantly lower than during the early spring. Summertime DMS concentrations were not significantly correlated to phytoplankton biomass (Chl a), pCO₂ or ??O₂/Ar. In contrast to the early spring time, there were no clear temporal trends in summertime gas concentrations. Rather, small-scale spatial variability, likely resulting from mixing and localized sea-ice melt, was clearly evident in surface gas distributions across the polynya. Analysis of length-scale dependent variability demonstrated that much of the spatial variance in surface water gases occurred at scales of <20 km, suggesting that high resolution analysis is needed to fully capture biogeochemical heterogeneity in this system.  相似文献   

长江口跨越锋面颗粒磷季节分布变化特征及影响因素   总被引：1，自引：0，他引：1  

刘希真  李宏亮  陈建芳  金海燕  王文亮  刘际弟  王奎  庄燕培 《海洋学研究》2011,(3):88-98

根据2006年夏、冬季以及2007年春、秋季“海监49号”科学考察船的调查数据,分析了长江口跨越锋面区域(31.00°～31.78°N、121.04°～123.99°E)颗粒总磷(PP),颗粒无机磷(PIP),颗粒有机磷(POP)的季节变化和空间分布特征.结果表明,PIP是水体颗粒磷的主要存在形式;受长江径流输沙量的影...  相似文献   

乐清湾水交换特征研究   总被引：4，自引：0，他引：4  

罗锋  廖光洪  杨成浩  徐晓华 《海洋学研究》2011,29(2):79-88

采用EFDC模式模拟研究了乐清湾水交换的三维过程和时空变化特征,并通过计算水示踪剂质量浓度分析水体置换过程。结果表明,乐清湾水交换主要是由鹿西岛两侧流入的外海水体与湾内水体的交换,以及乐清湾口门西侧附近的湾内水体与瓯江北口径流冲淡水之间的交换。从口门到湾顶,水交换能力差别较大。以最窄的连屿至打水山断面为界,以南水体1个月基本可以完全交换,而以北水体2个月后仍然无法交换至湾口水平。连屿至打水山断面以北地形复杂,岛屿较多,污染物主要通过岛屿间的潮汐汊道输运,断面的瓶颈效应也使得断面以北的水体交换能力稍弱。在口门附近90%以上的水体被外海置换所需时间不到5 d,而此时湾顶水质未有太大改变;15 d左右,80%湾内水体被外海水置换;90%湾内水体被置换仅需40 d;70 d时的水体置换率达97%。  相似文献   

关于水工结构工程专业国家自然科学基金研究热点的认识     

李炎隆 《水科学进展》2015,26(5):752-758

在国家自然科学基金委的资助下,中国的水利科学与海洋工程学科得到了长足发展.为进一步明确学科发展方向,正确指引水利学者的研究导向,基于国家自然科学基金委员会主办的"2014水工结构与水力装备战略研究暨青年学者学术交流会"及水利学科有关申请书的申请材料和专家评议意见,分析了水科学研究中水工结构工程学科近期的研究进展情况,初步明确了"库坝工程全寿命周期性能演变机理"为"十三五"期间水工结构学科重大研究项目,在"生态水工学"和"水利工程的信息化、数字化、智能化"为优先支持的跨学科交叉研究领域,提出了学科亟待攻关的前沿热点科学问题.该研究有利于科研工作者进一步凝炼关键科学问题,促进水利科学基础研究的发展.  相似文献   

基于全耦合的地表径流与土壤水分运动数值模拟   总被引：2，自引：0，他引：2       下载免费PDF全文

朱磊  田军仓  孙骁磊 《水科学进展》2015,26(3):322-330

针对降雨径流从坡面流下的过程中会发生下渗,导致土壤水非饱和带含水率增大这一动力学过程,从物理机制上对土壤水和地表水进行耦合,将二维平面地表水模型叠置在土壤水模型的顶部,对土壤水、地表水模型进行相同的空间和时间离散,在模型的计算过程中通过达西流关系对两者之间的水量交换进行计算(双层结点法耦合)或整合离散方程的整体法进行耦合。通过对两种耦合方法的比较以及与前人的实验结果对比,该模型与耦合方法能够准确地模拟和预测地表径流与土壤水分运动过程。研究结果可为分析地表水流与饱和-非饱和带水分与溶质耦合机理提供理论支持。  相似文献   

西湖总磷模型构建及内循环引水效果分析          下载免费PDF全文

滑磊  尤爱菊  韩曾萃  腾辉  朱军政 《水文》2015,35(4):27-32

调水是目前快速改善湖泊水质的有效方法之一,但是对于调水所能达到的最佳效果研究很少。以杭州西湖为例,利用环境流体动力学模型EFDC构建了西湖TP模型,对通过苏堤各桥孔的流量、外西湖分层流场和水质浓度进行了验证,分析了在现有外围调水情况下增加西湖内循环引水后西湖TP的时空变化。模拟结果表明,增加内循环引水,直接将低浓度区的水引至高浓度区,能够明显降低高浓度区的水质;低浓度区由于引水量的减小,区域内水质浓度会有一定的上升;全湖平均水质浓度基本不会发生改变。在没有增加外部引水的情况下,内循环引水可以使湖泊水体掺混更加均匀,对于防止高浓度区富营养化有很好的效果。增加内循环引水对西湖改善高浓度区水质有一定的指导意义,同时也可为相似湖泊增加内循环引水措施提供借鉴。  相似文献   

Estimation of turbulent sensible heat and momentum fluxes over a heterogeneous urban area using a large aperture scintillometer     

Sang-Hyun Lee  Jun-Ho Lee  Bo-Young Kim 《大气科学进展》2015,32(8):1092-1105

The accurate determination of surface-layer turbulent fluxes over urban areas is critical to understanding urban boundary layer (UBL) evolution. In this study, a remote-sensing technique using a large aperture scintillometer (LAS) was investigated to estimate surface-layer turbulent fluxes over a highly heterogeneous urban area. The LAS system, with an optical path length of 2.1 km, was deployed in an urban area characterized by a complicated land-use mix (residential houses, water body, bare ground, etc.). The turbulent sensible heat (Q H) and momentum fluxes (τ) were estimated from the scintillation measurements obtained from the LAS system during the cold season. Three-dimensional LAS footprint modeling was introduced to identify the source areas ("footprint") of the estimated turbulent fluxes. The analysis results showed that the LAS-derived turbulent fluxes for the highly heterogeneous urban area revealed reasonable temporal variation during daytime on clear days, in comparison to the land-surface process-resolving numerical modeling. A series of sensitivity tests indicated that the overall uncertainty in the LAS-derived daytime Q H was within 20%-30% in terms of the influence of input parameters and the non-dimensional similarity function for the temperature structure function parameter, while the estimation errors in τ were less sensitive to the factors of influence, except aerodynamic roughness length. The 3D LAS footprint modeling characterized the source areas of the LAS-derived turbulent fluxes in the heterogeneous urban area, revealing that the representative spatial scales of the LAS system deployed with the 2.1 km optical path distance ranged from 0.2 to 2 km2 (a "micro-α scale"), depending on local meteorological conditions.  相似文献